In an era of rapidly evolving Artificial Intelligence/Large Language Model (AI/LLM) technologies, cybersecurity practitioners face significant challenges in monitoring unauthorized AI solutions, detecting AI vulnerabilities, and identifying unexpected AI/LLM development. Tenable Security Center leverages advanced detection technologies - agents, passive network monitoring, dynamic application security testing, and distributed scan engines - to surface AI/LLM software, libraries, and browser plugins. The risk managers utilize these reports to begin a comprehensive review of the AI/LLM packages in systems and web applications, along with associated vulnerabilities, mitigating risks of exploitation, data leakage, and unauthorized resource consumption.